Advanced Hand Cleaner SDS

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Walnut Scrub Hand Soap 1.2 Relevant identified uses of the substance or mixture and uses advised against

Version number: GHS 1.0

SECTION 1: Identification

1.1 Product identifier

Relevant identified uses

HS code

  1. 1.3  Details of the supplier of the safety data sheet

    American Tribute Brand 5545 W. 56th Avenue Arvada CO 80002 619-347-0642

    www.americantributebrand.com

  2. 1.4  Emergency telephone number

    Emergency information service

SECTION 2: Hazard(s) identification

2.1 Classification of the substance or mixture

Date of compilation: 2023-02-21

Trade name

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) This mixture does not meet the criteria for classification.

  1. 2.2  Label elements

    Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word not required
    - Pictograms not required

  2. 2.3  Other hazards

    Special danger of slipping by leaking/spilling product. There is no additional information. Hazards not otherwise classified

    Harmful to aquatic life with long lasting effects (GHS category 3: aquatic toxicity - acute and/or chronic).

    Results of PBT and vPvB assessment
    Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.

Hand scrub Hand soap Professional use Industrial use

3402.39.90 .

USA 1.800.535.5053, INTL 1.352.323.3500 24 hr emergency information

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

Date of compilation: 2023-02-21

Endocrine disrupting properties
Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.

SECTION 3: Composition/information on ingredients

  1. 3.1  Substances

    Not relevant (mixture)

  2. 3.2  Mixtures

    Description of the mixture

Hazardous ingredients acc. to GHS

Name of substance

Identifier

Wt%

Classification acc. to GHS

Notes

ammonium polyac- ryloyldimethyl taurate

CAS No 58374-69-9

1 – < 10

Acute Tox. 4 / H302 cD / OSHA003

Sodium olefin sulfonate

CAS No 68439-57-6

1 – < 5

Skin Irrit. 2 / H315 Eye Dam. 1 / H318 HNOC001 HNOC006

For full text of abbreviations: see SECTION 16.

This table, if present, includes all GHS classified ingredients present above their cut-off limits, even if the finished product is not classified as hazard- ous by GHS.

SECTION 4: First-aid measures

4.1 Description of first-aid measures

General notes

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of un- consciousness place person in the recovery position. Never give anything by mouth.

Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air.

Following skin contact
Wash with plenty of soap and water.

Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing.

Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Date of compilation: 2023-02-21

Suitable extinguishing media
Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2)

  1. 5.2  Special hazards arising from the substance or mixture

    Hazardous combustion products
    Carbon monoxide (CO), Carbon dioxide (CO2)

  2. 5.3  Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow fire- fighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

  1. 6.1  Personal precautions, protective equipment and emergency procedures

    For non-emergency personnel Remove persons to safety.

    For emergency responders
    Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.

  2. 6.2  Environmental precautions

  3. 6.3  Methods and material for containment and cleaning up

    Advice on how to contain a spill Covering of drains

    Advice on how to clean up a spill
    Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder

    Appropriate containment techniques Use of adsorbent materials.

    Other information relating to spills and releases
    Place in appropriate containers for disposal. Ventilate affected area.

  4. 6.4  Reference to other sections

    Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Recommendations

Date of compilation: 2023-02-21

- Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Use only in well-ventilated areas.

Advice on general occupational hygiene

Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

  1. 7.2  Conditions for safe storage, including any incompatibilities

    Control of the effects

    Protect against external exposure, such as frost

  2. 7.3  Specific end use(s)

    See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits) this information is not available

Relevant DNELs of components of the mixture

Name of sub- stance

CAS No

End- point

Threshold level

Protection goal, route of expos- ure

Used in

Exposure time

Sodium olefin sulfon- ate

68439-57-6

DNEL

152.2 mg/m3

human, inhalatory

worker (industry)

chronic - systemic ef- fects

Sodium olefin sulfon- ate

68439-57-6

DNEL

2,158 mg/kg bw/day

human, dermal

worker (industry)

chronic - systemic ef- fects

Relevant PNECs of components of the mixture

Name of sub- stance

CAS No

End- point

Threshold level

Organism

Environmental compartment

Exposure time

Sodium olefin sulfon- ate

68439-57-6

PNEC

0.024 mg/l

aquatic organisms

freshwater

short-term (single in- stance)

Sodium olefin sulfon- ate

68439-57-6

PNEC

0.002 mg/l

aquatic organisms

marine water

short-term (single in- stance)

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Version number: GHS 1.0

Date of compilation: 2023-02-21

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Relevant PNECs of components of the mixture

Name of sub- stance

CAS No

End- point

Threshold level

Organism

Environmental compartment

Exposure time

Sodium olefin sulfon- ate

68439-57-6

PNEC

4 mg/l

aquatic organisms

sewage treatment plant (STP)

short-term (single in- stance)

Sodium olefin sulfon- ate

68439-57-6

PNEC

0.767 mg/kg

aquatic organisms

freshwater sediment

short-term (single in- stance)

Sodium olefin sulfon- ate

68439-57-6

PNEC

0.077 mg/kg

aquatic organisms

marine sediment

short-term (single in- stance)

Sodium olefin sulfon- ate

68439-57-6

PNEC

1.21 mg/kg

terrestrial organ- isms

soil

short-term (single in- stance)

8.2 Exposure controls

Appropriate engineering controls General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection Wear eye/face protection.

Skin protection

- Hand protection

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/imper- meability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special pur- poses, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other protection measures

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling.

Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Appearance

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Version number: GHS 1.0

Date of compilation: 2023-02-21

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Physical state

liquid (viscous)

Color

dark brown to black

Particle

not relevant (liquid)

Odor

spiced - woodsy

Other safety parameters

pH (value)

7.5 – 8.5 (25 °C)

Melting point/freezing point

not determined

Initial boiling point and boiling range

100 °C

Flash point

not determined

Evaporation rate

Not determined

Flammability (solid, gas)

not relevant, (fluid)

Vapor pressure

31.69 hPa at 25 °C

Density

0.9733 g/ml

Vapor density

this information is not available

Solubility(ies)

Partition coefficient

Auto-ignition temperature

9.2

- Water solubility

miscible in any proportion

- n-octanol/water (log KOW)

this information is not available

Viscosity

not determined

Explosive properties

none

Oxidizing properties

none

Other information

there is no additional information

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Version number: GHS 1.0

Date of compilation: 2023-02-21

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

SECTION 10: Stability and reactivity

  1. 10.1  Reactivity

    Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".

  2. 10.2  Chemical stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.

  1. 10.3  Possibility of hazardous reactions

    No known hazardous reactions.

  2. 10.4  Conditions to avoid

    There are no specific conditions known which have to be avoided.

  3. 10.5  Incompatible materials

    Oxidizers

  4. 10.6  Hazardous decomposition products

    Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Test data are not available for the complete mixture.

Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

This mixture does not meet the criteria for classification.

Acute toxicity
Shall not be classified as acutely toxic.

Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.

Serious eye damage/eye irritation
Shall not be classified as seriously damaging to the eye or eye irritant.

Respiratory or skin sensitization
Shall not be classified as a respiratory or skin sensitizer.

Acute toxicity estimate (ATE) of components of the mixture

Name of substance

CAS No

Exposure route

ATE

ammonium polyacryloyldimethyl taurate

58374-69-9

oral

2,000 mg/kg

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Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.

Carcinogenicity
Shall not be classified as carcinogenic.

Reproductive toxicity
Shall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).

Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).

Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1 Toxicity

Harmful to aquatic life with long lasting effects.

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

Date of compilation: 2023-02-21

Aquatic toxicity (acute) of components of the mixture

Name of substance

CAS No

Endpoint

Value

Species

Exposure time

Sodium olefin sulfonate

68439-57-6

LC50

4.2 mg/l

fish

96 h

Sodium olefin sulfonate

68439-57-6

EC50

4.53 mg/l

aquatic invertebrates

48 h

Sodium olefin sulfonate

68439-57-6

ErC50

5.2 mg/l

algae

72 h

ammonium polyac- ryloyldimethyl taurate

58374-69-9

LC50

>100 mg/l

rainbow trout (Onco- rhynchus mykiss)

96 h

ammonium polyac- ryloyldimethyl taurate

58374-69-9

EC50

>100 mg/l

daphnia magna

48 h

Aquatic toxicity (chronic) of components of the mixture

Name of substance

CAS No

Endpoint

Value

Species

Exposure time

Sodium olefin sulfonate

68439-57-6

EC50

230 mg/l

microorganisms

3h

12.2 Persistence and degradability

Data are not available.

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Version number: GHS 1.0

  1. 12.3  Bioaccumulative potential

    Data are not available.

  2. 12.4  Mobility in soil

    Data are not available.

Date of compilation: 2023-02-21

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

12.5 Results of PBT and vPvB assessment

According to the results of its assessment, this substance is not a PBT or a vPvB. Does not contain a PBT-/vPvB-substance in a con- centration of ≥ 0,1%.

  1. 12.6  Endocrine disrupting properties

    Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.

  2. 12.7  Other adverse effects

    Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packages
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.

Remarks

Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separ- ately by the local or national waste management facilities.

SECTION 14: Transport information

  1. 14.1  UN number

  2. 14.2  UN proper shipping name

  3. 14.3  Transport hazard class(es)

  4. 14.4  Packing group

  5. 14.5  Environmental hazards

  6. 14.6  Special precautions for user

    There is no additional information.

  7. 14.7  Transport in bulk according to IMO instruments

    The cargo is not intended to be carried in bulk.

not subject to transport regulations not relevant
none
not assigned

non-environmentally hazardous acc. to the dangerous goods regulations

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

Date of compilation: 2023-02-21

Information for each of the UN Model Regulations
Transport of dangerous goods by road or rail (49 CFR US DOT)

Not subject to transport regulations.

International Maritime Dangerous Goods Code (IMDG)

Not subject to IMDG.

International Civil Aviation Organization (ICAO-IATA/DGR)

Not subject to ICAO-IATA.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States)
Toxic Substance Control Act (TSCA)
all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III )

- The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304)

none of the ingredients are listed

- Specific Toxic Chemical Listings (EPCRA Section 313) none of the ingredients are listed

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)

- List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) none of the ingredients are listed

Clean Air Act

none of the ingredients are listed

Right to Know Hazardous Substance List

- Cleaning Product Right to Know Act Substance List (CA-RTK)

Name of substance

CAS No

Functionality

Authoritative Lists

water

7732-18-5

solvent

walnut shells, ground

84012-43-1

abrasive

Sodium olefin sulfonate

68439-57-6

surfactant

Glycerine

56-81-5

humectant

cocamidopropylhydroxysultaine

68139-30-0

surfactant

sodium sulfate

7757-82-6

cleaning agent

lauryl glucoside

110615-47-9

surfactant

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

Date of compilation: 2023-02-21

Name of substance

CAS No

Functionality

Authoritative Lists

D-Glucopyranose, oligomers, decyl octyl glycos- ides

68515-73-1

surfactant

dipropylene glycol

110-98-5

alcohols

C.I. Pigment Black 7

1333-86-4

colorant

IARC Carcinogens - 2B Prop 65

sodium chloride

7647-14-5

viscosity modifier

- Toxic or Hazardous Substance List (MA-TURA) none of the ingredients are listed

California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987

Proposition 65 List of chemicals

Name acc. to inventory

CAS No

Conc.

Remarks

Type of the toxicity

carbon black

1333-86-4

0.06 wt%

airborne, unbound particles of respirable size

cancer

VOC content

- Regulated Volatile Organic Compounds (VOC-EPA)
- Regulated Volatile Organic Compounds (VOC-Cal ARB)

Industry or sector specific available guidance(s)

NPCA-HMIS® III

Hazardous Materials Identification System. American Coatings Association.

0.004128 % 0.004089 %

Category

Rating

Description

Chronic

*

chronic (long-term) health effects may result from repeated overexposure

Health

0

no significant risk to health

Flammability

1

material that must be preheated before ignition can occur

Physical hazard

0

material that is normally stable, even under fire conditions, and will not react with water, poly- merize, decompose, condense, or self-react. Non-explosive

Personal protection

-

Chronic: Flammability: Health:
Personal protection: Physical hazard:

chronic hazard
flammability hazards
health hazard
personal protective equipment (PPE) for normal use reactivity

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

NFPA® 704

Date of compilation: 2023-02-21

National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Response (United States).

Category

Degree of hazard

Description

Flammability

1

material that must be preheated before ignition can occur

Health

0

material that, under emergency conditions, would offer no hazard beyond that of ordinary com- bustible material

Instability

0

material that is normally stable, even under fire conditions

Special hazard

National inventories

Country

Inventory

Status

CA

DSL

all ingredients are listed

EU

REACH Reg.

not all ingredients are listed

US

TSCA

all ingredients are listed as "ACTIVE"

AU

AIIC

all ingredients are listed

CN

IECSC

all ingredients are listed

EU

ECSI

not all ingredients are listed

JP

CSCL-ENCS

not all ingredients are listed

JP

ISHA-ENCS

not all ingredients are listed

KR

KECI

not all ingredients are listed

MX

INSQ

not all ingredients are listed

NZ

NZIoC

all ingredients are listed

PH

PICCS

not all ingredients are listed

TR

CICR

not all ingredients are listed

TW

TCSI

all ingredients are listed

Legend

AIIC
CICR CSCL-ENCS DSL
ECSI
IECSC INSQ ISHA-ENCS KECI
NZIoC PICCS

Australian Inventory of Industrial Chemicals
Chemical Inventory and Control Regulation
List of Existing and New Chemical Substances (CSCL-ENCS)
Domestic Substances List (DSL)
EC Substance Inventory (EINECS, ELINCS, NLP)
Inventory of Existing Chemical Substances Produced or Imported in China National Inventory of Chemical Substances
Inventory of Existing and New Chemical Substances (ISHA-ENCS)
Korea Existing Chemicals Inventory
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances (PICCS)

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REACH Reg. TCSI
TSCA

REACH registered substances Taiwan Chemical Substance Inventory Toxic Substance Control Act

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0 Legend

Date of compilation: 2023-02-21

15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information, including date of preparation or last revision

Indication of changes (revised safety data sheet)

Alignment to regulation: Globally Harmonized System of Classification and Labelling of Chemicals ("Purple book"). Restructuring: section 9, section 14

Abbreviations and acronyms

Abbr.

Descriptions of used abbreviations

49 CFR US DOT

49 CFR U.S. Department of Transportation

Acute Tox.

Acute toxicity

ATE

Acute Toxicity Estimate

Cal ARB

California Air Resources Board

CAS

Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

cD

Combustible dust

DGR

Dangerous Goods Regulations (see IATA/DGR)

DNEL

Derived No-Effect Level

EC50

Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval

EINECS

European Inventory of Existing Commercial Chemical Substances

ELINCS

European List of Notified Chemical Substances

EPA

Environmental Protection Agency. An agency of the federal government of the United States charged with protecting human health and the environment

ErC50

≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either growth (EbC50) or growth rate (ErC50) relative to the control

Eye Dam.

Seriously damaging to the eye

Eye Irrit.

Irritant to the eye

GHS

"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations

HS

Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the World Customs Or- ganisation)

IATA

International Air Transport Association

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Walnut Scrub Hand Soap

Version number: GHS 1.0

Date of compilation: 2023-02-21

Abbr.

Descriptions of used abbreviations

IATA/DGR

Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO

International Civil Aviation Organization

IMDG

International Maritime Dangerous Goods Code

LC50

Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 % lethality during a specified time interval

NLP

No-Longer Polymer

NPCA-HMIS® III

National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition

OSHA

Occupational Safety and Health Administration (United States)

PBT

Persistent, Bioaccumulative and Toxic

PNEC

Predicted No-Effect Concentration

Skin Corr.

Corrosive to skin

Skin Irrit.

Irritant to skin

VOC

Volatile Organic Compounds

vPvB

Very Persistent and very Bioaccumulative

Key literature references and sources for data

OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200.

Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Danger- ous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure

Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in section 2 and 3)

Disclaimer

This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.

Code

Text

H302

Harmful if swallowed.

H315

Causes skin irritation.

H318

Causes serious eye damage.

OSHA003

May form combustible dust concentrations in air.

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