Advanced Hand Cleaner SDS
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Walnut Scrub Hand Soap 1.2 Relevant identified uses of the substance or mixture and uses advised against
Version number: GHS 1.0
SECTION 1: Identification
1.1 Product identifier
Relevant identified uses
HS code
-
1.3 Details of the supplier of the safety data sheet
American Tribute Brand 5545 W. 56th Avenue Arvada CO 80002 619-347-0642
www.americantributebrand.com
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1.4 Emergency telephone number
Emergency information service
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixture
Date of compilation: 2023-02-21
Trade name
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) This mixture does not meet the criteria for classification.
-
2.2 Label elements
Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200) - Signal word not required
- Pictograms not required -
2.3 Other hazards
Special danger of slipping by leaking/spilling product. There is no additional information. Hazards not otherwise classified
Harmful to aquatic life with long lasting effects (GHS category 3: aquatic toxicity - acute and/or chronic).
Results of PBT and vPvB assessment
Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%.
Hand scrub Hand soap Professional use Industrial use
3402.39.90 .
USA 1.800.535.5053, INTL 1.352.323.3500 24 hr emergency information
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
Date of compilation: 2023-02-21
Endocrine disrupting properties
Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.
SECTION 3: Composition/information on ingredients
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3.1 Substances
Not relevant (mixture)
-
3.2 Mixtures
Description of the mixture
Hazardous ingredients acc. to GHS |
||||
Name of substance |
Identifier |
Wt% |
Classification acc. to GHS |
Notes |
ammonium polyac- ryloyldimethyl taurate |
CAS No 58374-69-9 |
1 – < 10 |
Acute Tox. 4 / H302 cD / OSHA003 |
|
Sodium olefin sulfonate |
CAS No 68439-57-6 |
1 – < 5 |
Skin Irrit. 2 / H315 Eye Dam. 1 / H318 HNOC001 HNOC006 |
For full text of abbreviations: see SECTION 16.
This table, if present, includes all GHS classified ingredients present above their cut-off limits, even if the finished product is not classified as hazard- ous by GHS.
SECTION 4: First-aid measures
4.1 Description of first-aid measures
General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of un- consciousness place person in the recovery position. Never give anything by mouth.
Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. Provide fresh air.
Following skin contact
Wash with plenty of soap and water.
Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing.
Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Date of compilation: 2023-02-21
Suitable extinguishing media
Water spray, Alcohol resistant foam, BC-powder, Carbon dioxide (CO2)
-
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2) -
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow fire- fighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance.
SECTION 6: Accidental release measures
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6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel Remove persons to safety.
For emergency responders
Wear breathing apparatus if exposed to vapors/dust/aerosols/gases. -
6.2 Environmental precautions
-
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill Covering of drains
Advice on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binderAppropriate containment techniques Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area. -
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Recommendations
Date of compilation: 2023-02-21
- Measures to prevent fire as well as aerosol and dust generation Use local and general ventilation. Use only in well-ventilated areas.
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
-
7.2 Conditions for safe storage, including any incompatibilities
Control of the effects
Protect against external exposure, such as frost
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7.3 Specific end use(s)
See section 16 for a general overview.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limit values (Workplace Exposure Limits) this information is not available
Relevant DNELs of components of the mixture |
||||||
Name of sub- stance |
CAS No |
End- point |
Threshold level |
Protection goal, route of expos- ure |
Used in |
Exposure time |
Sodium olefin sulfon- ate |
68439-57-6 |
DNEL |
152.2 mg/m3 |
human, inhalatory |
worker (industry) |
chronic - systemic ef- fects |
Sodium olefin sulfon- ate |
68439-57-6 |
DNEL |
2,158 mg/kg bw/day |
human, dermal |
worker (industry) |
chronic - systemic ef- fects |
Relevant PNECs of components of the mixture |
||||||
Name of sub- stance |
CAS No |
End- point |
Threshold level |
Organism |
Environmental compartment |
Exposure time |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
0.024 mg/l |
aquatic organisms |
freshwater |
short-term (single in- stance) |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
0.002 mg/l |
aquatic organisms |
marine water |
short-term (single in- stance) |
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Version number: GHS 1.0
Date of compilation: 2023-02-21
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Relevant PNECs of components of the mixture |
||||||
Name of sub- stance |
CAS No |
End- point |
Threshold level |
Organism |
Environmental compartment |
Exposure time |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
4 mg/l |
aquatic organisms |
sewage treatment plant (STP) |
short-term (single in- stance) |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
0.767 mg/kg |
aquatic organisms |
freshwater sediment |
short-term (single in- stance) |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
0.077 mg/kg |
aquatic organisms |
marine sediment |
short-term (single in- stance) |
Sodium olefin sulfon- ate |
68439-57-6 |
PNEC |
1.21 mg/kg |
terrestrial organ- isms |
soil |
short-term (single in- stance) |
8.2 Exposure controls
Appropriate engineering controls General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection Wear eye/face protection.
Skin protection
- Hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/imper- meability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special pur- poses, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
- Other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling.
Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties Appearance
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Version number: GHS 1.0
Date of compilation: 2023-02-21
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Physical state |
liquid (viscous) |
Color |
dark brown to black |
Particle |
not relevant (liquid) |
Odor |
spiced - woodsy |
Other safety parameters
pH (value) |
7.5 – 8.5 (25 °C) |
Melting point/freezing point |
not determined |
Initial boiling point and boiling range |
100 °C |
Flash point |
not determined |
Evaporation rate |
Not determined |
Flammability (solid, gas) |
not relevant, (fluid) |
Vapor pressure |
31.69 hPa at 25 °C |
Density |
0.9733 g/ml |
Vapor density |
this information is not available |
Solubility(ies)
Partition coefficient
Auto-ignition temperature
9.2
- Water solubility |
miscible in any proportion |
- n-octanol/water (log KOW) |
this information is not available |
Viscosity |
not determined |
Explosive properties |
none |
Oxidizing properties |
none |
Other information |
there is no additional information |
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Version number: GHS 1.0
Date of compilation: 2023-02-21
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
SECTION 10: Stability and reactivity
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10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
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10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
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10.3 Possibility of hazardous reactions
No known hazardous reactions.
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10.4 Conditions to avoid
There are no specific conditions known which have to be avoided.
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10.5 Incompatible materials
Oxidizers
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10.6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Test data are not available for the complete mixture.
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)
This mixture does not meet the criteria for classification.
Acute toxicity
Shall not be classified as acutely toxic.
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Shall not be classified as seriously damaging to the eye or eye irritant.
Respiratory or skin sensitization
Shall not be classified as a respiratory or skin sensitizer.
Acute toxicity estimate (ATE) of components of the mixture |
|||
Name of substance |
CAS No |
Exposure route |
ATE |
ammonium polyacryloyldimethyl taurate |
58374-69-9 |
oral |
2,000 mg/kg |
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Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
SECTION 12: Ecological information
12.1 Toxicity
Harmful to aquatic life with long lasting effects.
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
Date of compilation: 2023-02-21
Aquatic toxicity (acute) of components of the mixture |
|||||
Name of substance |
CAS No |
Endpoint |
Value |
Species |
Exposure time |
Sodium olefin sulfonate |
68439-57-6 |
LC50 |
4.2 mg/l |
fish |
96 h |
Sodium olefin sulfonate |
68439-57-6 |
EC50 |
4.53 mg/l |
aquatic invertebrates |
48 h |
Sodium olefin sulfonate |
68439-57-6 |
ErC50 |
5.2 mg/l |
algae |
72 h |
ammonium polyac- ryloyldimethyl taurate |
58374-69-9 |
LC50 |
>100 mg/l |
rainbow trout (Onco- rhynchus mykiss) |
96 h |
ammonium polyac- ryloyldimethyl taurate |
58374-69-9 |
EC50 |
>100 mg/l |
daphnia magna |
48 h |
Aquatic toxicity (chronic) of components of the mixture |
|||||
Name of substance |
CAS No |
Endpoint |
Value |
Species |
Exposure time |
Sodium olefin sulfonate |
68439-57-6 |
EC50 |
230 mg/l |
microorganisms |
3h |
12.2 Persistence and degradability
Data are not available.
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Version number: GHS 1.0
-
12.3 Bioaccumulative potential
Data are not available.
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12.4 Mobility in soil
Data are not available.
Date of compilation: 2023-02-21
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
12.5 Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB. Does not contain a PBT-/vPvB-substance in a con- centration of ≥ 0,1%.
-
12.6 Endocrine disrupting properties
Does not contain an endocrine disruptor (EDC) in a concentration of ≥ 0,1%.
-
12.7 Other adverse effects
Data are not available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packages
Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separ- ately by the local or national waste management facilities.
SECTION 14: Transport information
-
14.1 UN number
-
14.2 UN proper shipping name
-
14.3 Transport hazard class(es)
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14.4 Packing group
-
14.5 Environmental hazards
-
14.6 Special precautions for user
There is no additional information.
-
14.7 Transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
not subject to transport regulations not relevant
none
not assigned
non-environmentally hazardous acc. to the dangerous goods regulations
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
Date of compilation: 2023-02-21
Information for each of the UN Model Regulations
Transport of dangerous goods by road or rail (49 CFR US DOT)
Not subject to transport regulations.
International Maritime Dangerous Goods Code (IMDG)
Not subject to IMDG.
International Civil Aviation Organization (ICAO-IATA/DGR)
Not subject to ICAO-IATA.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States)
Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III )
- The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304)
none of the ingredients are listed
- Specific Toxic Chemical Listings (EPCRA Section 313) none of the ingredients are listed
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
- List of Hazardous Substances and Reportable Quantities (CERCLA section 102a) (40 CFR 302.4) none of the ingredients are listed
Clean Air Act
none of the ingredients are listed
Right to Know Hazardous Substance List
- Cleaning Product Right to Know Act Substance List (CA-RTK)
Name of substance |
CAS No |
Functionality |
Authoritative Lists |
water |
7732-18-5 |
solvent |
|
walnut shells, ground |
84012-43-1 |
abrasive |
|
Sodium olefin sulfonate |
68439-57-6 |
surfactant |
|
Glycerine |
56-81-5 |
humectant |
|
cocamidopropylhydroxysultaine |
68139-30-0 |
surfactant |
|
sodium sulfate |
7757-82-6 |
cleaning agent |
|
lauryl glucoside |
110615-47-9 |
surfactant |
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
Date of compilation: 2023-02-21
Name of substance |
CAS No |
Functionality |
Authoritative Lists |
D-Glucopyranose, oligomers, decyl octyl glycos- ides |
68515-73-1 |
surfactant |
|
dipropylene glycol |
110-98-5 |
alcohols |
|
C.I. Pigment Black 7 |
1333-86-4 |
colorant |
IARC Carcinogens - 2B Prop 65 |
sodium chloride |
7647-14-5 |
viscosity modifier |
- Toxic or Hazardous Substance List (MA-TURA) none of the ingredients are listed
California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987
Proposition 65 List of chemicals |
||||
Name acc. to inventory |
CAS No |
Conc. |
Remarks |
Type of the toxicity |
carbon black |
1333-86-4 |
0.06 wt% |
airborne, unbound particles of respirable size |
cancer |
VOC content
- Regulated Volatile Organic Compounds (VOC-EPA)
- Regulated Volatile Organic Compounds (VOC-Cal ARB)
Industry or sector specific available guidance(s)
NPCA-HMIS® III
Hazardous Materials Identification System. American Coatings Association.
0.004128 % 0.004089 %
Category |
Rating |
Description |
Chronic |
* |
chronic (long-term) health effects may result from repeated overexposure |
Health |
0 |
no significant risk to health |
Flammability |
1 |
material that must be preheated before ignition can occur |
Physical hazard |
0 |
material that is normally stable, even under fire conditions, and will not react with water, poly- merize, decompose, condense, or self-react. Non-explosive |
Personal protection |
- |
Chronic: Flammability: Health:
Personal protection: Physical hazard:
chronic hazard
flammability hazards
health hazard
personal protective equipment (PPE) for normal use reactivity
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
NFPA® 704
Date of compilation: 2023-02-21
National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Response (United States).
Category |
Degree of hazard |
Description |
Flammability |
1 |
material that must be preheated before ignition can occur |
Health |
0 |
material that, under emergency conditions, would offer no hazard beyond that of ordinary com- bustible material |
Instability |
0 |
material that is normally stable, even under fire conditions |
Special hazard |
National inventories
Country |
Inventory |
Status |
CA |
DSL |
all ingredients are listed |
EU |
REACH Reg. |
not all ingredients are listed |
US |
TSCA |
all ingredients are listed as "ACTIVE" |
AU |
AIIC |
all ingredients are listed |
CN |
IECSC |
all ingredients are listed |
EU |
ECSI |
not all ingredients are listed |
JP |
CSCL-ENCS |
not all ingredients are listed |
JP |
ISHA-ENCS |
not all ingredients are listed |
KR |
KECI |
not all ingredients are listed |
MX |
INSQ |
not all ingredients are listed |
NZ |
NZIoC |
all ingredients are listed |
PH |
PICCS |
not all ingredients are listed |
TR |
CICR |
not all ingredients are listed |
TW |
TCSI |
all ingredients are listed |
Legend
AIIC
CICR CSCL-ENCS DSL
ECSI
IECSC INSQ ISHA-ENCS KECI
NZIoC PICCS
Australian Inventory of Industrial Chemicals
Chemical Inventory and Control Regulation
List of Existing and New Chemical Substances (CSCL-ENCS)
Domestic Substances List (DSL)
EC Substance Inventory (EINECS, ELINCS, NLP)
Inventory of Existing Chemical Substances Produced or Imported in China National Inventory of Chemical Substances
Inventory of Existing and New Chemical Substances (ISHA-ENCS)
Korea Existing Chemicals Inventory
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
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REACH Reg. TCSI
TSCA
REACH registered substances Taiwan Chemical Substance Inventory Toxic Substance Control Act
Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0 Legend
Date of compilation: 2023-02-21
15.2 Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information, including date of preparation or last revision
Indication of changes (revised safety data sheet)
Alignment to regulation: Globally Harmonized System of Classification and Labelling of Chemicals ("Purple book"). Restructuring: section 9, section 14
Abbreviations and acronyms
Abbr. |
Descriptions of used abbreviations |
49 CFR US DOT |
49 CFR U.S. Department of Transportation |
Acute Tox. |
Acute toxicity |
ATE |
Acute Toxicity Estimate |
Cal ARB |
California Air Resources Board |
CAS |
Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances) |
cD |
Combustible dust |
DGR |
Dangerous Goods Regulations (see IATA/DGR) |
DNEL |
Derived No-Effect Level |
EC50 |
Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50 % changes in response (e.g. on growth) during a specified time interval |
EINECS |
European Inventory of Existing Commercial Chemical Substances |
ELINCS |
European List of Notified Chemical Substances |
EPA |
Environmental Protection Agency. An agency of the federal government of the United States charged with protecting human health and the environment |
ErC50 |
≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either growth (EbC50) or growth rate (ErC50) relative to the control |
Eye Dam. |
Seriously damaging to the eye |
Eye Irrit. |
Irritant to the eye |
GHS |
"Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations |
HS |
Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the World Customs Or- ganisation) |
IATA |
International Air Transport Association |
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Safety Data Sheet
acc. to 29 CFR 1910.1200 App D
Walnut Scrub Hand Soap
Version number: GHS 1.0
Date of compilation: 2023-02-21
Abbr. |
Descriptions of used abbreviations |
IATA/DGR |
Dangerous Goods Regulations (DGR) for the air transport (IATA) |
ICAO |
International Civil Aviation Organization |
IMDG |
International Maritime Dangerous Goods Code |
LC50 |
Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 % lethality during a specified time interval |
NLP |
No-Longer Polymer |
NPCA-HMIS® III |
National Paint and Coatings Association: Hazardous Materials Identification System - HMIS® III, Third Edition |
OSHA |
Occupational Safety and Health Administration (United States) |
PBT |
Persistent, Bioaccumulative and Toxic |
PNEC |
Predicted No-Effect Concentration |
Skin Corr. |
Corrosive to skin |
Skin Irrit. |
Irritant to skin |
VOC |
Volatile Organic Compounds |
vPvB |
Very Persistent and very Bioaccumulative |
Key literature references and sources for data
OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200.
Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Danger- ous Goods Regulations (DGR) for the air transport (IATA).
Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (additivity formula).
List of relevant phrases (code and full text as stated in section 2 and 3)
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.
Code |
Text |
H302 |
Harmful if swallowed. |
H315 |
Causes skin irritation. |
H318 |
Causes serious eye damage. |
OSHA003 |
May form combustible dust concentrations in air. |
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