CLP+ SDS

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Riptide CLP
1.2 Relevant identified uses of the substance or mixture and uses advised against

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

SECTION 1: Identification

1.1 Product identifier

Relevant identified uses

3. 1.3  Details of the supplier of the safety data sheet

   American Tribute Brand 5545 W. 56th Avenue Arvada CO 80002 619-347-0642

   www.americantributebrand.com

4. 1.4  Emergency telephone number

   Emergency information service

SECTION 2: Hazard(s) identification

2.1 Classification of the substance or mixture

Revision: 2022-07-06

Trade name

Professional use Industrial use

USA 1.800.535.5053, INTL 1.352.323.3500 24 hr emergency information

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

Supplemental hazard information

For full text of abbreviations: see SECTION 16.

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The most important adverse physicochemical, human health and environmental effects The product is combustible and can be ignited by potential ignition sources.

2.2 Label elements

Labelling acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

• -  Signal word

• -  Pictograms

  GHS07, GHS08

• -  Hazard statements H227

  H304 H315 H336

danger

Combustible liquid.
May be fatal if swallowed and enters airways. Causes skin irritation.
May cause drowsiness or dizziness.

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

- Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 If swallowed: Immediately call a poison center/doctor.
P302+P352 If on skin: Wash with plenty of water.
P304+P340 If inhaled: Remove person to fresh air and keep comfortable for breathing.
P312 Call a poison center/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P331 Do NOT induce vomiting.
P362 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

- Hazardous ingredients for labelling napthenic oil, severely hydrotreated, odorless mineral spirits, distillates (petroleum) hydrotreated, light

2.3 Other hazards

This material is combustible, but will not ignite readily. Hazards not otherwise classified

May be harmful in contact with skin (GHS category 5: acutely toxic - dermal).
May be harmful if inhaled (GHS category 5: acutely toxic - inhalation).
Toxic to aquatic life with long lasting effects (GHS category 2: aquatic toxicity - acute and/or chronic).

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

SECTION 3: Composition/information on ingredients

1. 3.1  Substances

   Not relevant (mixture)

2. 3.2  Mixtures

   Description of the mixture

For full text of abbreviations: see SECTION 16. Exact percentage of ingredients is withheld as a trade secret.

This table, if present, includes all GHS classified ingredients present above their cut-off limits, even if the finished product is not classified as hazard- ous by GHS.

SECTION 4: First-aid measures

4.1 Description of first-aid measures

General notes

Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of un- consciousness place person in the recovery position. Never give anything by mouth.

Following inhalation

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irrita- tion, consult a physician. Provide fresh air.

Following skin contact
Wash with plenty of soap and water.

Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing.

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Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.

SECTION 5: Fire-fighting measures

1. 5.1  Extinguishing media

   Suitable extinguishing media
   Water spray, BC-powder, Carbon dioxide (CO2)

2. 5.2  Special hazards arising from the substance or mixture

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

In case of insufficient ventilation and/or in use, may form flammable/explosive vapor-air mixture. Solvent vapors are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures.

Hazardous combustion products
Carbon monoxide (CO), Carbon dioxide (CO2)

5.3 Advice for firefighters

In case of fire and/or explosion do not breathe fumes. Coordinate firefighting measures to the fire surroundings. Do not allow fire- fighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

1. 6.1  Personal precautions, protective equipment and emergency procedures

   For non-emergency personnel Remove persons to safety.

   For emergency responders
   Wear breathing apparatus if exposed to vapors/dust/aerosols/gases.

2. 6.2  Environmental precautions

   If substance has entered a water course or sewer, inform the responsible authority.

3. 6.3  Methods and material for containment and cleaning up

   Advice on how to contain a spill Covering of drains

   Advice on how to clean up a spill
   Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder

   Appropriate containment techniques Use of adsorbent materials.

   Other information relating to spills and releases
   Place in appropriate containers for disposal. Ventilate affected area.

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

6.4 Reference to other sections

Revision: 2022-07-06

Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

1. 7.1  Precautions for safe handling

   Recommendations

   • -  Measures to prevent fire as well as aerosol and dust generation

     Use local and general ventilation. Avoidance of ignition sources. Keep away from sources of ignition - No smoking. Take precaution- ary measures against static discharge. Use only in well-ventilated areas. Due to danger of explosion, prevent leakage of vapours in- to cellars, flues and ditches. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools.

   • -  Specific notes/details

     Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are particularly prone to the presence of flammable substances or mixtures. Vapors are heavier than air, spread along floors and form explosive mix- tures with air. Vapors may form explosive mixtures with air.

     Advice on general occupational hygiene

     Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.

2. 7.2  Conditions for safe storage, including any incompatibilities

   Managing of associated risks

   • -  Explosive atmospheres
     Keep container tightly closed and in a well-ventilated place. Use local and general ventilation. Keep cool. Protect from sunlight.

   • -  Flammability hazards

     Keep away from sources of ignition - No smoking. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Protect from sunlight.

   • -  Ventilation requirements
     Use local and general ventilation. Ground/bond container and receiving equipment.

   • -  Packaging compatibilities
     Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used.

3. 7.3  Specific end use(s)

   See section 16 for a general overview.

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Notation

Ceiling-C ceiling value is a limit value above which exposure should not occur
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless other-

wise specified)
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-weighted aver-

age (unless otherwise specified

8.2 Exposure controls

Appropriate engineering controls General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection Wear eye/face protection.

Skin protection

- Hand protection

Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/imper- meability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special pur- poses, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other protection measures

Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. Wash hands thoroughly after handling.

Respiratory protection
In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Appearance

Other safety parameters

Explosive limits

Partition coefficient

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

9.2 Other information

SECTION 10: Stability and reactivity

10.1 Reactivity

Revision: 2022-07-06

Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". The mixture contains reactive substance(s). Risk of ignition.

If heated:
Risk of ignition

2. 10.2  Chemical stability

   See below "Conditions to avoid".

3. 10.3  Possibility of hazardous reactions

   No known hazardous reactions.

4. 10.4  Conditions to avoid

   Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

   Hints to prevent fire or explosion

   Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

5. 10.5  Incompatible materials

   Oxidizers

6. 10.6  Hazardous decomposition products

   Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known. Hazardous combustion products: see section 5.

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Revision: 2022-07-06

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Test data are not available for the complete mixture.

Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

Classification acc. to OSHA "Hazard Communication Standard" (29 CFR 1910.1200)

Acute toxicity
Shall not be classified as acutely toxic.

GHS of the United Nations, annex 4: May be harmful in contact with skin or if inhaled.

Skin corrosion/irritation Causes skin irritation.

Serious eye damage/eye irritation
Shall not be classified as seriously damaging to the eye or eye irritant.

Respiratory or skin sensitization
Shall not be classified as a respiratory or skin sensitizer.

Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.

Carcinogenicity
Shall not be classified as carcinogenic.

Reproductive toxicity
Shall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposure May cause drowsiness or dizziness.

Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Aspiration hazard
May be fatal if swallowed and enters airways.

SECTION 12: Ecological information

12.1 Toxicity

Toxic to aquatic life with long lasting effects.

Revision: 2022-07-06

2. 12.2  Persistence and degradability

   Data are not available.

3. 12.3  Bioaccumulative potential

   Data are not available.

4. 12.4  Mobility in soil

   Data are not available.

5. 12.5  Results of PBT and vPvB assessment

   Data are not available.

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

6. 12.6  Endocrine disrupting properties

   None of the ingredients are listed.

7. 12.7  Other adverse effects

   Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Waste treatment-relevant information Solvent reclamation/regeneration.

Revision: 2022-07-06

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.

Waste treatment of containers/packages

Only packagings which are approved (e.g. acc. to DOT) may be used. Completely emptied packages can be recycled. Handle con- taminated packages in the same way as the substance itself.

Remarks

Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separ- ately by the local or national waste management facilities.

SECTION 14: Transport information

1. 14.1  UN number

   DOT IMDG-Code ICAO-TI

2. 14.2  UN proper shipping name

   DOT IMDG-Code

   ICAO-TI
   Technical name (hazardous ingredients)

3. 14.3  Transport hazard class(es)

   DOT IMDG-Code ICAO-TI

UN 3082 UN 3082 UN 3082

Environmentally hazardous substance, liquid, n.o.s.

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Environmentally hazardous substance, liquid, n.o.s.

napthenic oil, severely hydrotreated, odorless mineral spirits

9 9 9

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

4. 14.4  Packing group

   DOT IMDG-Code ICAO-TI

5. 14.5  Environmental hazards

   Environmentally hazardous substance (aquatic environment)

6. 14.6  Special precautions for user

   There is no additional information.

7. 14.7  Transport in bulk according to IMO instruments

   The cargo is not intended to be carried in bulk.

Revision: 2022-07-06

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

III

III

III

hazardous to the aquatic environment

Information for each of the UN Model Regulations
Transport of dangerous goods by road or rail (49 CFR US DOT)

Not regulated under DOT until packaged in single containers larger than 119 gallons each - liquid, or 882 lbs each - solid.

napthenic oil, severely hydrotreated, odorless mineral spirits

Particulars in the shipper's declaration

Reportable quantity (RQ) Danger label(s)

UN3082, Environmentally hazardous substance, liquid, n.o.s., (contains: napthenic oil, severely hydrotreated, odorless mineral spirits), 9, III

68,965,517 lbs (31,310,345 kg) (methanol) 9, fish and tree

Environmental hazards
Special provisions (SP)
ERG No
International Maritime Dangerous Goods Code (IMDG)

Marine pollutant Danger label(s)

Special provisions (SP) Excepted quantities (EQ) Limited quantities (LQ)

yes (hazardous to the aquatic environment) (napthenic oil, severely hy- drotreated)

9, fish and tree

274, 335, 969 E1
5 L

yes (hazardous to the aquatic environment)
8, 146, 173, 335, IB3, T4, TP1, TP29 171

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

EmS
Stowage category
International Civil Aviation Organization (ICAO-IATA/DGR)

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

Environmental hazards Danger label(s)

Special provisions (SP) Excepted quantities (EQ) Limited quantities (LQ)

SECTION 15: Regulatory information

yes (hazardous to the aquatic environment) 9, fish and tree

A97, A158, A197 E1
30 kg

F-A, S-F A

15.1 Safety, health and environmental regulations specific for the product in question National regulations (United States)
Toxic Substance Control Act (TSCA) all ingredients are listed Superfund Amendment and Reauthorization Act (SARA TITLE III )

- The List of Extremely Hazardous Substances and Their Threshold Planning Quantities (EPCRA Section 302, 304)

none of the ingredients are listed

Clean Air Act

none of the ingredients are listed

Right to Know Hazardous Substance List

- Cleaning Product Right to Know Act Substance List (CA-RTK)

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

- Hazardous Substances List (MN-ERTK)

Legend

Revision: 2022-07-06

A American Conference of Governmental Industrial Hygienists (ACGIH), "Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices for 1992-93", available from ACGIH

O Occupational Safety and Health Administration (OSHA), Safety and Health Standards, Code of Federal Regulations, title 29, part 1910, sub- part Z, "Toxic and Hazardous Substances, 1990." General information: Minnesota Department of Labor and Industry, Occupational Safety and Health Division

California Environmental Protection Agency (Cal/EPA): Proposition 65 - Safe Drinking Water and Toxic Enforcement Act of 1987

VOC content

- Regulated Volatile Organic Compounds (VOC-EPA)
- Regulated Volatile Organic Compounds (VOC-Cal ARB)

Industry or sector specific available guidance(s)

NPCA-HMIS® III

Hazardous Materials Identification System. American Coatings Association.

35.01 % 35.01 %

Chronic: Flammability: Health:
Personal protection: Physical hazard:

chronic hazard
flammability hazards
health hazard
personal protective equipment (PPE) for normal use reactivity

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

NFPA® 704

Revision: 2022-07-06

National Fire Protection Association: Standard System for the Identification of the Hazards of Materials for Emergency Response (United States).

National inventories

Legend

AIIC
CICR CSCL-ENCS DSL
ECSI
IECSC INSQ
KECI
NZIoC PICCS REACH Reg.

Australian Inventory of Industrial Chemicals
Chemical Inventory and Control Regulation
List of Existing and New Chemical Substances (CSCL-ENCS)
Domestic Substances List (DSL)
EC Substance Inventory (EINECS, ELINCS, NLP)
Inventory of Existing Chemical Substances Produced or Imported in China National Inventory of Chemical Substances
Korea Existing Chemicals Inventory
New Zealand Inventory of Chemicals
Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH registered substances

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Legend

TCSI Taiwan Chemical Substance Inventory TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

Revision: 2022-07-06

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information, including date of preparation or last revision

Indication of changes (revised safety data sheet)

Alignment to regulation: Globally Harmonized System of Classification and Labelling of Chemicals ("Purple book"). Restructuring: section 9, section 14

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

Abbreviations and acronyms

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Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

Key literature references and sources for data

OSHA Hazard Communication Standard (HCS), 29 CFR 1910.1200.

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Version number: GHS 3.0
Replaces version of: 2022-06-20 (GHS 2)

Revision: 2022-07-06

Safety Data Sheet

acc. to 29 CFR 1910.1200 App D

Riptide CLP

Transport of dangerous goods by road or rail (49 CFR US DOT). International Maritime Dangerous Goods Code (IMDG). Danger- ous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure

Physical and chemical properties: The classification is based on tested mixture.
Health hazards, Environmental hazards: The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in section 2 and 3)

Disclaimer

This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.

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